Copper damascene is the dominant interconnect fabrication method using copper metal fill in damascene-patterned dielectric trenches and vias. Why copper: Cu resistivity (1.7 uOhm-cm) is ~40% lower than Al (2.7 uOhm-cm). Better electromigration resistance. Enables faster, more reliable interconnects. Cu challenge: Cannot be dry-etched by conventional RIE. Must use damascene (inlaid) approach. Diffuses rapidly in Si and SiO2, requiring barriers. Process sequence: Etch dielectric features, PVD TaN/Ta barrier, PVD Cu seed, electroplate Cu fill, Cu CMP (multi-step), post-CMP clean, cap layer deposition. Electroplating: Bottom-up fill using electrochemical deposition with accelerator/suppressor/leveler additives. Superfill provides void-free filling of high-AR features. Barrier: TaN provides diffusion barrier, Ta provides Cu adhesion and promotes (111) texture for electromigration resistance. CMP: Multi-step - bulk Cu removal, barrier removal, buff. Slurry chemistry with BTA inhibitor controls dishing. Cap layer: SiCN or SiN capping layer over Cu prevents oxidation and Cu diffusion into next dielectric level. Also serves as etch stop. Electromigration: Cu has higher EM resistance than Al. Bamboo grain structure and proper interfaces extend EM lifetime. Adoption: First production use by IBM at 220nm node (1997). Now universal for interconnect.
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